Iodidotris(triphenylphosphine)copper(I) acetonitrile solvate
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چکیده
منابع مشابه
Iodidotris(triphenylphosphine)copper(I) acetonitrile solvate
The title compound, [CuI(C(18)H(15)P)(3)]·C(2)H(3)N, was obtained from the reaction of triphenyl-phosphine and copper(I) iodide in acetonitrile. The monomeric form of the complex has slightly distorted coordination of Cu by the I atom and three P atoms. The crystal structure is stabilized by C-H⋯π inter-actions between phenyl H atoms and phenyl rings. In addition, the complex mol-ecules exhibit...
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In the sulfone mol-ecule of the title compound, C(12)H(12)N(2)O(2)S·C(2)H(3)N, the two benzene rings are oriented at a dihedral angle of 80.69 (3)°. Weak intra-molecular C-H⋯O hydrogen bonds result in the formation of two five-membered rings, which both have envelope conformations. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules.
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In the crystal structure of the title compound, C(14)H(16)N(4)O(2) (2+)·2Cl(-)·CH(3)CN, weak inter-molecular N-H⋯Cl hydrogen bonds are found between the H atoms bound to the pyridine and amine N atoms and the chloride anions. The asymmetric unit consits of one half cationic mol-ecule which is located on a centre of inversion, one chloride anion in a general position and one half acetonitrile mo...
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In the crystal structure of the title compound, [Co(C(12)H(8)N(2))(3)](BF(4))(2)·CH(3)CN, the mol-ecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π-π [centroid-centroid = 3.542 (4) Å] and two C-H⋯π inter-actions [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808007174